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Beilstein J. Org. Chem. 2015, 11, 1985–1990, doi:10.3762/bjoc.11.214
Graphical Abstract
Scheme 1: Non-catalyzed addition of P–H species to alkenes.
Figure 1: ORTEP drawing (30% thermal ellipsoid) of phosphine oxide 3d. A CIF file with the crystallographic d...
Scheme 2: Addition of secondary phosphine sulfide to vinyl sulfide under aerobic catalyst-free conditions.
Scheme 3: Putative mechanism.